Bordeaux to Barcelona in 5 days

A friend and myself have booked an Easyjet flight to Bordeaux and a return easyjet flight from Barcelona at the beginning of June. We have 5 full cycling days and now just have to plan the best route. Google maps indicate approx 350 miles, so 70 miles a day on average although I suspect this could vary a lot depending on the route chosen and availability of accommodation. Crossing the Pyrenees will be the highlight so we want to pick the best route accross. We will be travelling on road bikes with panniers (assuming they survive the flight!!) but looking to stay in cheap B&Bs or hostels. Any help with planning the route would be very much appreciated and any thoughts on stuff to pack.
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There are more cols than you can shake a stick at but this is one of the more direct ones from France to Spain.
Pack a corkscrew and a cheese knife.
The cols are fantastic. Our rout from Barcelona to the Pyrenees was via the c-59 to mola then c-25 and c-17 up across to ripoll. From ripoll the n152 takes you to French border via the collada de tosses. Bourge madam is the crossing point I think. Then down to ax les thermes.
Spanish side was much harder to navigate. I would suggest google street viewing your road choices as we ended up sat at the slip ways of a few motorways scratching our heads!
Good luck!
www.seeyouinspain.co.uk