Please help with my gears

in Workshop
Hi guys, I’m having an issue with my gears, when I have the front mech on the largest cog (outer) and the rear on the largest cog (inside) and I pedal backwards gently the chain drops from the largest rear gear down 2 gears. I cannot figure it out it’s frying my brain, does anyone have any experience in this area that may be able to offer some advice, I have searched the net but I don’t seem to be able to find the issue.
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Guys
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Guys
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The chain line is poor so when you pedal backwards, releasing the tension, the chain drops down the cassette. Cross chaining puts a lot of side strain on the chain and cassette so will result in more rapid wear. Big-big probably pulls the derailleur too far forward too, and if the chain is a bit short can be catastrophic.
Is there actually any proof that it causes a problem with doubles?