Chain not shifting onto inner ring properly

Hi,
Following a bike rebuild and new chain, I'm finding that the chain will occasionally skip over or balance on the edge of the inner ring of my double chain ring. The dérailleur alignment seems ok, so I suspect it may be the chain length. Could the chain be too long?
Following a bike rebuild and new chain, I'm finding that the chain will occasionally skip over or balance on the edge of the inner ring of my double chain ring. The dérailleur alignment seems ok, so I suspect it may be the chain length. Could the chain be too long?
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Might not be that mind, mine did the same at it was using all 8 speed equipment. Did it once or twice and then never again so didn't worry about it.
2010 Cube Agree SL
2010 Cube Agree SL
I don't think I've been clear in my original post. It's the inner ring of the chainset that the chain occasionally misses. It's a Dura-ace 53/39 double.