Chain trying to jump to another gear on backpedal

Had my bike serviced recently and new chain and cassette fitted. When I backpedal the chain try's to jump to another gear on the cassette and jams. Is this an adjustment problem? Set up is 105 with Ultegra rear dérailleur.
Current Steed: 02 Marin Tiburon
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But dont back pedal more than you have to.