chain keeps kicking up

im determined to learn some basic bike tuning so i got myself a good stand and tools.im trying to adjust the rear mech which i've managed to do with the help of numerous web vids but ive one slight problem , the when im on high gears and large chainset the chain kicks up off the top of the chainset every few revolutions, like skips a beat so to speak.
ive noticed the outside edge of a link will sometimes actually sit right on the edge chainset and rise up off the chainset and looks as though its trying to come off.
im not sure if the chains right length or not or how i can fix this , can anyone help me resolve this problem.
ive noticed the outside edge of a link will sometimes actually sit right on the edge chainset and rise up off the chainset and looks as though its trying to come off.
im not sure if the chains right length or not or how i can fix this , can anyone help me resolve this problem.
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You may have adjusted your limit screws too far and thus its forcing the chain onto the edge of the rear sprocket.